{"id":1354,"date":"2019-03-31T11:24:39","date_gmt":"2019-03-31T03:24:39","guid":{"rendered":"http:\/\/www.chinadeai.com\/?p=1354"},"modified":"2019-03-18T11:25:29","modified_gmt":"2019-03-18T03:25:29","slug":"wu-shui-chu-li-chang-zhong-jin-shu-wu-ran-te-dian-ji-qian-zai-feng-xian","status":"publish","type":"post","link":"http:\/\/www.chinadeai.com\/1354.html\/","title":{"rendered":"\u6c61\u6c34\u5904\u7406\u5382\u91cd\u91d1\u5c5e\u6c61\u67d3\u7279\u70b9\u53ca\u6f5c\u5728\u98ce\u9669"},"content":{"rendered":"
\u6750\u6599\u4e0e\u65b9\u6cd5<\/p>\n
2.1 \u6c61\u6ce5\u6837\u54c1\u7684\u91c7\u96c6\u4e0e\u9884\u5904\u7406<\/p>\n
\u6c61\u6ce5\u53d6\u81ea\u5317\u4eac\u5e02\u67d0\u6c61\u6c34\u5904\u7406\u5382\u6c61\u6ce5\u8131\u6c34\u8f66\u95f4\uff0c\u4e3a\u5747\u5300\u53cd\u6620\u6c61\u6ce5\u91cd\u91d1\u5c5e\u542b\u91cf\u60c5\u51b5\uff0c\u8fde\u7eed\u53d6\u68377 d\u5e76\u5206\u522b\u6807\u8bb0\u4e3aS1~S7.\u6bcf\u6b21\u53d6\u6837500 g\u4e8e\u805a\u4e59\u70ef\u81ea\u5c01\u888b\u53d6\u56de\uff0c\u6837\u54c1\u5728\u901a\u98ce\u9634\u51c9\u5904\u81ea\u7136\u98ce\u5e72\u540e\u6df7\u5300\uff0c\u7528\u56db\u5206\u6cd5\u591a\u6b21\u7b5b\u9009\u540e\u53d630 g \u6c61\u6ce5\u6837\u54c1\uff0c\u7814\u78e8\u8fc7150 \u03bcm\u5c3c\u9f99\u7b5b(100\u76ee)\uff0c\u88c5\u5165\u5bc6\u5c01\u888b\u6807\u53f7\u5907\u7528.<\/p>\n
2.2 \u6837\u54c1\u5904\u7406\u4e0e\u6d4b\u8bd5<\/p>\n
2.2.1 \u542b\u91cf\u5206\u6790<\/p>\n
\u79f0\u53d6\u6837\u54c10.2 g\uff0c\u7f6e\u4e8e\u805a\u56db\u6c1f\u4e59\u70ef\u6d88\u89e3\u7f50\u4e2d\uff0c\u6ef4\u52a02~3\u6ef4\u53bb\u79bb\u5b50\u6c34\u6da6\u6e7f\uff0c\u52a06 mL\u785d\u9178\u30016 mL\u6c22\u6c1f\u9178\u53ca2 mL\u76d0\u9178\uff0c\u8bbe\u5b9a\u5fae\u6ce2\u6d88\u89e3\u7a0b\u5e8f\u6d88\u89e3\uff0c\u6d88\u89e3\u540e\u5728\u7535\u70ed\u677f\u4e0a\u52a0\u70ed\u8d76\u9178\uff0c\u51b7\u5374\u52a01%\u785d\u9178\u5b9a\u5bb9\u81f350 mL\uff0c\u4e8e4 \u2103\u4e0b\u4fdd\u5b58\u5f85\u6d4b.<\/p>\n
2.2.2 \u91cd\u91d1\u5c5e\u5f62\u6001\u5206\u6790\u65b9\u6cd5<\/p>\n
\u5e38\u7528\u7684\u5f62\u6001\u5206\u6790\u65b9\u6cd5\u5305\u62ecTessier\u9010\u7ea7\u63d0\u53d6\u6cd5\u548cBCR\u9010\u7ea7\u63d0\u53d6\u6cd5\uff0cTessier\u63d0\u53d6\u6cd5\u5206\u7ea7\u66f4\u8be6\u7ec6\uff0c\u4f46BCR\u63d0\u53d6\u6cd5\u91cd\u73b0\u6027\u76f8\u5bf9\u8f83\u597d.\u91cd\u91d1\u5c5e\u5143\u7d20\u5316\u5b66\u5f62\u6001\u5206\u6790\u91c7\u7528\u6b27\u5171\u4f53\u4fee\u6b63\u7684BCR\u987a\u5e8f\u63d0\u53d6\u6cd5\uff1a<\/p>\n
\u2460\u9178\u53ef\u63d0\u53d6\u6001\uff1a\u79f0\u53d60.50 g\u571f\u58e4\u523050 mL\u79bb\u5fc3\u7ba1\u4e2d\uff0c\u52a0\u516520 mL 0.11 mol \u00b7 L-1\u918b\u9178(HOAc)\uff0c\u5ba4\u6e29\u632f\u836116 h\uff0c\u57283000 r \u00b7 min-1\u7684\u8f6c\u901f\u4e0b\u79bb\u5fc320 min\uff0c\u53d6\u4e0a\u6e05\u6db2\u5f85\u6d4b\uff0c\u6b8b\u6e23\u7559\u5b58;<\/p>\n
\u2461\u53ef\u8fd8\u539f\u6001\uff1a\u5411\u4e0a\u4e00\u6b65\u7684\u6b8b\u6e23\u4e2d\u52a00.5 mol \u00b7 L-1\u7684NH2OH \u00b7 HCL\u6eb6\u6db2(\u76d0\u9178\u7f9f\u80fa)20 mL\uff0c\u5ba4\u6e29\u632f\u836116 h\uff0c\u57283000 r \u00b7 min-1\u7684\u8f6c\u901f\u4e0b\u79bb\u5fc320 min\uff0c\u53d6\u4e0a\u6e05\u6db2\u5f85\u6d4b\uff0c\u6b8b\u6e23\u7559\u5b58;<\/p>\n
\u2462\u53ef\u6c27\u5316\u6001\uff1a\u5411\u4e0a\u4e00\u6b65\u7684\u6b8b\u6e23\u4e2d\u52a030%\u7684H2O2 5 mL\uff0c\u5ba4\u6e29\u53cd\u5e941h\uff0c\u5076\u5c14\u632f\u8361\uff0c(85\u00b12)\u2103\u4e0b\u6c34\u6d74\u785d\u53161 h\uff0c\u84b8\u53d1\u81f3\u4f53\u79ef\u5c11\u4e8e2 mL\uff0c\u8865\u52a05 mL H2O2\uff0c\u91cd\u590d\u4e0a\u8ff0\u64cd\u4f5c\uff0c\u4f53\u79ef\u51cf\u5c11\u5230\u5927\u7ea61 mL;\u51b7\u5374\u540e\u52a01.0 mol \u00b7 L-1 NH4OAc\u6eb6\u6db225 mL\uff0c\u5ba4\u6e29\u4e0b\u632f\u836116 h\uff0c\u57283000 r \u00b7 min-1\u8f6c\u901f\u4e0b\u79bb\u5fc320 min\uff0c\u53d6\u4e0a\u6e05\u6db2\u5f85\u6d4b\uff0c\u6b8b\u6e23\u7559\u5b58;<\/p>\n
\u2463\u6b8b\u6e23\u6001\uff1a\u65b9\u6cd5\u540c\u5168\u91cf\u68c0\u6d4b\u65b9\u6cd5.<\/p>\n
2.3 \u5206\u6790\u65b9\u6cd5<\/p>\n
2.3.1 \u6c61\u6ce5\u91cd\u91d1\u5c5e\u6c61\u67d3\u8bc4\u4ef7<\/p>\n
\u5355\u56e0\u5b50\u6307\u6570\u6cd5\uff1a\u5355\u56e0\u5b50\u6307\u6570\u6cd5\u662f\u56fd\u5185\u5916\u666e\u904d\u91c7\u7528\u7684\u65b9\u6cd5\u4e4b\u4e00\uff0c\u662f\u5bf9\u571f\u58e4\u4e2d\u67d0\u4e00\u6c61\u67d3\u7269\u7684\u6c61\u67d3\u7a0b\u5ea6\u8fdb\u884c\u8bc4\u4ef7\uff0c\u5176\u8ba1\u7b97\u516c\u5f0f\u4e3a\uff1a<\/p>\n
<\/p>\n
\u5185\u6885\u7f57\u7efc\u5408\u6c61\u67d3\u6307\u6570\u6cd5\uff1a\u5185\u6885\u7f57\u7efc\u5408\u6c61\u67d3\u6307\u6570\u6cd5\u53ef\u5168\u9762\u53cd\u6620\u571f\u58e4\u4e2d\u5404\u6c61\u67d3\u7269\u7684\u5e73\u5747\u6c61\u67d3\u6c34\u5e73\uff0c\u4e5f\u7a81\u51fa\u4e86\u6c61\u67d3\u6700\u4e25\u91cd\u7684\u6c61\u67d3\u7269\u7ed9\u73af\u5883\u9020\u6210\u7684\u5371\u5bb3\uff0c\u5176\u8ba1\u7b97\u516c\u5f0f\u4e3a\uff1a<\/p>\n
<\/p>\n
\u88681 \u571f\u58e4\u91cd\u91d1\u5c5e\u6c61\u67d3\u5206\u7ea7\u6807\u51c6<\/p>\n
<\/p>\n
\u88682 \u571f\u58e4\u73af\u5883\u8d28\u91cf\u6267\u884c\u6807\u51c6\u503c<\/p>\n
<\/p>\n
\u6c89\u79ef\u7269\u91cd\u91d1\u5c5e\u6f5c\u5728\u751f\u6001\u98ce\u9669\u8bc4\u4ef7\u91c7\u7528\u745e\u5178\u79d1\u5b66\u5bb6Hakanson \u63d0\u51fa\u7684\u8bc4\u4ef7\u65b9\u6cd5\uff0c\u8be5\u65b9\u6cd5\u7efc\u5408\u8003\u8651\u4e86\u591a\u5143\u7d20\u534f\u540c\u4f5c\u7528\u3001\u6bd2\u6027\u6c34\u5e73\u3001\u6c61\u67d3\u6d53\u5ea6\u53ca\u73af\u5883\u5bf9\u91cd\u91d1\u5c5e\u6c61\u67d3\u654f\u611f\u6027\u7b49\u56e0\u7d20\uff0c\u6d88\u9664\u4e86\u533a\u57df\u5dee\u5f02\u53ca\u5f02\u6e90\u6c61\u67d3\u7684\u5f71\u54cd\uff0c\u5df2\u6210\u4e3a\u76ee\u524d\u6c89\u79ef\u7269\u91cd\u91d1\u5c5e\u6c61\u67d3\u8d28\u91cf\u8bc4\u4ef7\u5e94\u7528\u5e7f\u6cdb\u7684\u4e00\u79cd\u65b9\u6cd5\u8ba1\u7b97\u516c\u5f0f\u5982\u4e0b\uff1a<\/p>\n
<\/p>\n
\u88683 \u4e0d\u540c\u91cd\u91d1\u5c5e\u7684\u6bd2\u6027\u6548\u5e94\u7cfb\u6570<\/p>\n
<\/p>\n
<\/p>\n
\u53c2\u8003\u571f\u58e4\u91cd\u91d1\u5c5e\u8bc4\u4ef7\u6a21\u578b\uff0c\u672c\u7814\u7a76\u8bbe\u5b9a2\u79cd\u66b4\u9732\u9014\u5f84\uff1a\u2460\u901a\u8fc7\u624b-\u53e3\u76f4\u63a5\u6444\u5165;\u2461\u901a\u8fc7\u76ae\u80a4\u63a5\u89e6\u6444\u5165.\u5176\u4e2d\uff0c\u624b-\u53e3\u6444\u98df\u9014\u5f84\u548c\u76ae\u80a4\u63a5\u89e6\u9014\u5f84\u4e0b\u7684\u6444\u5165\u91cf(AOD)\u8ba1\u7b97\u516c\u5f0f\u5206\u522b\u5982\u5f0f(6)\u548c(7)\u6240\u793a.<\/p>\n
<\/p>\n
\u88685 \u5065\u5eb7\u98ce\u9669\u8bc4\u4ef7\u6a21\u578b\u66b4\u9732\u53c2\u6570<\/p>\n
<\/p>\n
\u5355\u4e2a\u6c61\u67d3\u7269\u5355\u4e00\u66b4\u9732\u9014\u5f84\u7684\u975e\u81f4\u764c\u98ce\u9669\u4ee5 HQ\u8868\u793a\uff0c\u591a\u6c61\u67d3\u7269\u591a\u9014\u5f84\u8054\u5408\u975e\u81f4\u764c\u98ce\u9669\u4ee5 HI\u8868\u793a\uff0c\u8ba1\u7b97\u516c\u5f0f\u5206\u522b\u5982\u4e0b\uff1a<\/p>\n
<\/p>\n
\u6c61\u67d3\u7269\u81f4\u764c\u98ce\u9669\u503c\u5219\u4ee5R\u8868\u793a\uff0c\u5f53\u66b4\u9732\u4eba\u7fa4\u5904\u4e8e\u4f4e\u98ce\u9669\u6c34\u5e73(\u4f30\u7b97\u98ce\u9669\u503c\u57280.01\u4ee5\u4e0b)\u65f6\uff0c\u91c7\u7528\u7ebf\u6027\u4f4e\u5242\u91cf\u81f4\u764c\u98ce\u9669\u6a21\u578b\uff0c\u8ba1\u7b97\u516c\u5f0f\u89c1\u5f0f(10);\u5f53\u66b4\u9732\u4eba\u7fa4\u5904\u4e8e\u9ad8\u98ce\u9669\u6c34\u5e73(\u4f30\u7b97\u98ce\u9669\u503c\u9ad8\u4e8e0.01)\u65f6\uff0c\u91c7\u7528\u4e00\u6b21\u51b2\u51fb\u6a21\u578b\uff0c\u8ba1\u7b97\u516c\u5f0f\u89c1\u5f0f(11).<\/p>\n
<\/p>\n
<\/p>\n
\u88686 SF\u548cRfD \u53c2\u8003\u503c<\/p>\n
<\/p>\n
\u6750\u6599\u4e0e\u65b9\u6cd5 2.1 \u6c61\u6ce5\u6837\u54c1\u7684\u91c7\u96c6\u4e0e\u9884\u5904\u7406 \u6c61\u6ce5\u53d6\u81ea\u5317\u4eac\u5e02\u67d0\u6c61\u6c34\u5904\u7406\u5382\u6c61\u6ce5\u8131\u6c34\u8f66\u95f4\uff0c\u4e3a\u5747\u5300\u53cd\u6620\u6c61\u6ce5\u91cd\u91d1\u5c5e\u542b\u91cf\u60c5 […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[100],"_links":{"self":[{"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/posts\/1354"}],"collection":[{"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/comments?post=1354"}],"version-history":[{"count":0,"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/posts\/1354\/revisions"}],"wp:attachment":[{"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/media?parent=1354"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/categories?post=1354"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.chinadeai.com\/wp-json\/wp\/v2\/tags?post=1354"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}